The same current that piles up shells brings fish through, which is why there are usually lines in the water here at first and last light. Anglers work the shore and the rocks near the jetty for snook and redfish in particular, and the pass has a long local reputation for both.
A few practical notes if you are fishing rather than shelling. A Florida saltwater fishing licence is required for shore fishing unless you are exempt — check the current rules before you travel rather than assuming. The rocks are uneven and get slick. And the pass is a working channel with boat traffic moving through it, so keep casts clear.
For sunset, this is one of the better positions on the island because you get two shorelines in the frame — Sanibel behind you, Captiva across the water — rather than an unbroken horizon. The bridge gives the composition a structure that an open beach does not.
Come for the last hour of light rather than the last ten minutes. The lot is small, the angle changes fast, and the shell bank looks its best when the sun is low enough to rake across it.